Table 3. Characterization of the polymer coated nanoparticles.
Particle a | SPRmax [nm] | d DLS b [nm] | Cloud point c [°C] |
Bare Au 15 nm | 520 | 18 | — |
PNIPAM25@Au15 | 524 | 24 | — |
PNIPAM50@Au15 | 524 | 32 | 74 |
PNIPAM100@Au15 | 525 | 37 | 55 |
Bare Au 40 nm | 526 | 42 | — |
PNIPAM25@Au40 | 530 | 50 | — |
PNIPAM50@Au40 | 531 | 56 | 80 |
PNIPAM100@Au40 | 531 | 61 | 60 |
a X@Au m : X = polymer coating used; m = diameter of gold nanoparticle.
b d DLS(nm): Z-average diameter as determined by DLS.
c Measured in PBS upon heating from 25 °C to 85 °C, 0.029 mg mL–1 total gold concentration.