Skip to main content
. 2016 Sep 12;113(39):10932–10937. doi: 10.1073/pnas.1609724113

Table 1.

Chromatographic, UV-visible, and MS characteristics of main carotenoids from tissues of Honduran white bats E. alba

Peak Carotenoid tR (min) λmax (nm) [M+H]+* Main product ions
1 (L, E+n-l) Lutein 15.7 420, 444, 472 569.4335 (−3.1/28.8) 551.4281 [M+H-18]+; 495.3642
2 (E+n-l) Dilauroyl-5,6-epoxy-lutein 33.8 418, 443, 469 949.7668 (2.6/42.3) 931.7601 [M+H-H2O]+; 749.5791 [M+H-FA]+
549.4184 [M+H-2FA]+
3 (E+n-l) Unknown 35.3 420, 444, 472
4 (E+n-l) Lauroyl-myristoyl-5,6-epoxy-lutein 36.2 418, 443, 469 977.7970 (−1.4/39.2) 959.7912 [M+H-H2O]+; 777.6150 [M+H-FA]+
749.5890 [M+H-FA]+; 549.4179 [M+H-2FA]+
5 (E+n-l) Myristoyl-oleyl-5,6-epoxy-lutein 37.1 418, 443, 469 1,059.8695 (−2.9/45.6) 1,041.8592 [M+H-H2O]+; 831.6697 [M+H-FA]+
777.6196 [M+H-FA]+;549.4162 [M+H-2FA]+
6 (E+n-l) Lauroyl-linoleoyl-lutein 45.5 420, 444, 472 1,013.8339 (−1.96/29.3) 995.8237 [M+H-H2O]+; 813.6589 [M+H-FA]+
733.5929 [M+H-FA]+; 533.4187 [M+H-2FA]+
7 (E+n-l) Palmitoyl-linoleoyl-lutein§ 46.3 420, 444, 472 1,067.8813 (1.74/30.2) 1,049.9804 [M+H-H2O]+; 811.6524 [M+H-FA]+
789.6613 [M+H-FA]+; 533.4249 [M+H-2FA]+
8 (E+n-l) Palmitoyl-linoleoyl-lutein§ 47.0 420, 444, 472 1,067.8859 (1.84/29.5) 1,049.9797 [M+H-H2O]+; 811.6537 [M+H-FA]+
789.6595 [M+H-FA]+; 533.4262 [M+H-2FA]+
9 (E+n-l) Palmitoyl-linoleoyl-lutein§ 47.5 420, 444, 472 1,067.8806 (1.06/32.8) 1,049.9992 [M+H-H2O]+; 811.6529 [M+H-FA]+
789.6604 [M+H-FA]+; 533.4236 [M+H-2FA]+
10 (E+n-l) Oleyl-linoleoyl-lutein 48.4 420, 444, 472 1,095.9183 (1.35/19.8) 1,077.9015 [M+H-H2O]+; 813.6593 [M+H-FA]+
815.6758 [M+H-FA]+;533.4278 [M+H-2FA]+
*

m/z experimental value of the molecular ion. Numbers in parenthesis are mass error in ppm and SigmaFit value.

Main products ion arising from MS2-based reactions.

Peak present in liver extract (L) and/or in ears+nose-leaf (E+n-l) extract.

Peak not identified.

§

Trans and cis isomers.