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. 2016 Oct 7;7:13066. doi: 10.1038/ncomms13066

Table 1. Properties of p(gNDI-T2) and p(gNDI-gT2).

Polymer IP* [eV] EA* [eV] Bandgap ΔE=IP−EA Absorption onset [nm] Repeating units [NMR]
p(gNDI-T2) 5.53 3.85 1.68 817
p(gNDI-gT2) 4.83 4.12 0.71 1,550 7

Ionization potential (IP), electron affinity (EA) and bandgap measured by cyclic voltammetry (CV) of a thin film in 0.1 M TBAPF6 (ACN) acetonitrile solution.

*CV measurements of the films with the onset energy value for oxidation and reduction peak.

End capping for p(gNDI-T2) could not be carried out due to a low solubility of the polymer.

The number of repeating units was calculated by 1H NMR spectroscopy as well as MALDI-TOF spectrometry.