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A family of potent metalloinsertors. (top) Structure of four metalloinsertors containing an unusual Rh-O coordination. (bottom) Overlay of the inserting chrysi ligands of planar [Rh(bpy)2(chrysi)]3+ (pink) and buckled [Rh(DPE)(chrysi)(phen)]2+ (blue). DPE, bpy, and phen ligands have been removed for clarity. Adapted from [64]
