Table 2.
Compound | RIa | Relative peak area (%) |
Odorb | |||||
Control | Hr | Sx | Hn | Gs | Hf | |||
Aldehydes | ||||||||
(E)-2-Butenal | 1028 | – | 0.91 | – | – | – | – | – |
Hexanal | 1081 | 5.78 | 1.39 | 1.94 | 2.95 | 2.96 | 2.13 | Green |
Heptanal | 1183 | – | – | – | 0.64 | – | – | Planty green |
(E)-2-Heptenal | 1318 | 1.06 | – | 1.21 | 1.04 | 1.69 | 0.89 | Fatty |
Nonanal | 1392 | – | – | 0.41 | 1.02 | 1.70 | 0.69 | Slightly floral |
Furfural | 1460 | – | 2.05 | 7.81 | 2.22 | 4.13 | 6.49 | – |
Benzaldehyde | 1515 | 13.27 | 6.78 | 9.38 | 8.56 | 4.62 | 5.83 | Bitter almond |
Total | 20.11 | 11.13 | 20.75 | 16.43 | 15.10 | 16.03 | ||
Alcohols | ||||||||
Ethanol | 925 | – | 32.40 | 9.15 | 18.01 | 13.19 | 11.72 | Alcoholic, strong |
3-Methyl-1-butanol | 1198 | – | 2.13 | 1.30 | 8.25 | – | – | Sweet, green |
1-Pentanol | 1247 | 7.01 | 1.05 | 1.27 | 1.00 | 4.26 | 1.71 | Alcoholic |
1-Hexanol | 1361 | 19.71 | 26.52 | 28.29 | 15.12 | 25.74 | 36.89 | – |
1-Heptanol | 1448 | – | – | 3.99 | – | 4.35 | – | – |
1-Octanol | 1551 | 1.42 | 1.32 | 2.17 | 0.41 | 1.69 | 1.85 | – |
Phenylethyl alcohol | 1903 | – | 3.06 | 3.38 | 27.58 | 7.96 | 2.95 | – |
Total | 28.14 | 66.48 | 49.55 | 70.37 | 57.19 | 55.12 | ||
Ketones | ||||||||
2-Pentanone | 978 | – | 0.63 | – | – | – | – | Fruity |
3-Hydroxy-2-butanone | 1292 | – | 1.22 | – | – | 2.91 | – | – |
Total | 0.00 | 1.85 | 0.00 | 0.00 | 2.91 | 0.00 | ||
Acids | ||||||||
Acetic acid | 1449 | – | 9.02 | 14.03 | 4.60 | 18.84 | 18.17 | Vinegar, acid |
Hexanoic acid | 1855 | – | 0.90 | 4.85 | 0.41 | 0.97 | 1.56 | – |
Total | 0.00 | 9.92 | 18.88 | 5.01 | 19.81 | 19.73 | ||
Others | ||||||||
2-Pentylfuran | 1231 | 43.95 | 9.68 | 9.14 | 4.88 | 3.77 | 9.12 | Fruity, green |
Naphthalene | 1740 | 7.80 | 0.95 | 1.37 | 2.46 | 1.23 | – | Camphoric |
Total | 51.75 | 10.63 | 10.51 | 7.34 | 5.00 | 9.12 |
Retention indices on DB-Wax column;
Odor perceived at the sniffing port