Table 1. Performance of CV, DPV and OECT in the detection of AA, DA and UA.
Three electrode cell |
OECT |
|||||
---|---|---|---|---|---|---|
CV |
DPV |
|||||
Epaa (V vs SCE) | Sensitivityb(LOD)c | Sensitivityb(LOD)c | Sensitivitye | Sensitivityd(LOD)c | Sensitivitye | |
AA | 0.29 | 0.063 ± 0.005(1 10−4) | 0.00967 ± 0.0003(2 10−5) | 0.193 ± 0.003 | 0.102 ± 0.004(7 10−5) | 0.85 ± 0.03 |
DA | 0.35 | 0.109 ± 0.009(3 10−4) | 0.448 ± 0.006(2 10−6) | 9.0 ± 0.1 | 1.09 ± 0.04(6 10−6) | 9.1 ± 0.3 |
UA | 0.41 | 0.090 ± 0.002(2 10−4) | 0.065 ± 0.001(6 10−6) | 1.30 ± 0.02 | 0.40 ± 0.01(2 10−5) | 3.33 ± 0.08 |
aanodic peak potentials evaluated by CV for 1 mM solutions.
bexpressed in A M−1 cm−2.
cexpressed in M.
dexpressed in S M−1.
enormalized sensitivity expressed in S M−1 cm−2. The DPV and OECT sensitivities are normalized to pulse amplitude and gate area, respectively.