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. 2016 Oct 20;6:35764. doi: 10.1038/srep35764

Table 4. Association constants (Ka ψ) obtained from non-linear programme and the corresponding thermodynamic parameters ΔH and ΔS of different vitamin-β-cyclodextrin inclusion complexes.

  Temp/Ka Kaψ × 10−3/M−1b ΔH/kJ mol−1b ΔS/J mol−1K−1b
Nicotinic acid 288.15 1.66 −21.28 −12.23
293.15 1.43
298.15 1.23
303.15 1.06
308.15 0.93
313.15 0.82
Ascorbic acid 288.15 4.21 −21.83 −6.40
293.15 3.61
298.15 3.06
303.15 2.64
308.15 2.35
313.15 2.03

aStandard uncertainties in temperature u are: u(T) = ±0.01 K.

bMean errors in Kaψ = ±0.01 × 10−3 M−1; ΔH = ±0.01 kJ mol−1; ΔS = ±0.01 J mol−1K−1.