Table 4. Association constants (Ka ψ) obtained from non-linear programme and the corresponding thermodynamic parameters ΔHoψ and ΔSoψ of different vitamin-β-cyclodextrin inclusion complexes.
| Temp/Ka | Kaψ × 10−3/M−1b | ΔHoψ/kJ mol−1b | ΔSoψ/J mol−1K−1b | |
|---|---|---|---|---|
| Nicotinic acid | 288.15 | 1.66 | −21.28 | −12.23 |
| 293.15 | 1.43 | |||
| 298.15 | 1.23 | |||
| 303.15 | 1.06 | |||
| 308.15 | 0.93 | |||
| 313.15 | 0.82 | |||
| Ascorbic acid | 288.15 | 4.21 | −21.83 | −6.40 |
| 293.15 | 3.61 | |||
| 298.15 | 3.06 | |||
| 303.15 | 2.64 | |||
| 308.15 | 2.35 | |||
| 313.15 | 2.03 |
aStandard uncertainties in temperature u are: u(T) = ±0.01 K.
bMean errors in Kaψ = ±0.01 × 10−3 M−1; ΔHoψ = ±0.01 kJ mol−1; ΔSoψ = ±0.01 J mol−1K−1.