Table 1. AuNC Acceptor and Donor Optical Properties.
Φ | Abs(max, nm) | Em(max, nm) | ɛ (M−1cm−1) | τ (s) | kr0 (s−1) | knr0(s−1) | |
---|---|---|---|---|---|---|---|
AuNC | 0.06 | — | 820* | 4.5 × 104 (520 nm) | 7.5 × 10−7 | 8.0 × 104 | 1.3 × 106 |
Cy3 | 0.09 | 550 | 570 | 1.5 × 105 | 5.7 × 10−10 | 1.6 × 108 | 1.6 × 109 |
R-Red | 0.20 | 570 | 580 | 1.3 × 105 | 2.8 × 10−9 | 7.2 × 107 | 2.9 × 108 |
Ru(bpy) | 0.07 | 445 | 615 | 1.8 × 104 | 3.9 × 10−7 | 1.8 × 105 | 2.4 × 106 |
Tb(chelate) | 0.30 | 343 | 545 | 1.3 × 104 | 9.1 × 10−4 | 3.3 × 102 | 7.7 × 102 |
QD545 | 0.16 | 533 | 545 | 1.6 × 105 | 7.3 × 10−9 | 2.2 × 107 | 1.2 × 108 |
QD625 | 0.50 | 611 | 625 | 5.0 × 105 | 6.1 × 10−8 | 8.2 × 106 | 8.2 × 106 |
Φ = quantum yield, Abs(max) = maximum absorption peak/QD first absorption band, Em(max) = maximum emission wavelength, ɛ = extinction coefficient, τ = amplitude weighted averaged lifetime, kr0 = radiative decay rate, knr0 = nonradiative decay rate. *FWHM ~220 nm.