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. Author manuscript; available in PMC: 2017 Apr 27.
Published in final edited form as: J Am Chem Soc. 2016 Apr 15;138(16):5341–5350. doi: 10.1021/jacs.6b01706

Scheme 1.

Scheme 1

Stoichiometric conversion of 4-N2 into 1 under catalytically relevant conditions. A proposed reaction pathway is shown along the dashed arrows. “P3BFe-H+” is a plausible intermediate of this conversion but has not been thoroughly characterized.