Table 2.
13C NMR spectroscopic data for 1 and 2
| No. | 1 a | 2 b | 2 c |
|---|---|---|---|
| 1 | 16.6, CH2 | 16.4, CH2 | 16.3, CH2 |
| 2 | 24.3, CH2 | 24.0, CH2 | 24.1, CH2 |
| 3 | 142.7, CH | 142.8, CH | 143.1, CH |
| 4 | 134.4, C | 133.8, C | 133.9, C |
| 5 | 39.5, C | 39.1, C | 39.1, C |
| 6 | 82.8, CH | 83.9, CH | 82.6, CH |
| 7 | 29.6, CH2 | 29.4, CH2 | 29.2, CH2 |
| 8 | 46.8, CH | 47.7/47.4, CH | 47.1/46.8, CH |
| 9 | 39.8, C | 39.4, C | 39.4, C |
| 10 | 45.8, CH | 44.5/45.0, CH | 45.0/45.6, CH |
| 11 | 47.7, CH2 | 44.1/44.6, CH2 | 44.9/44.1, CH2 |
| 12 | 69.5, CH | 64.6, CH | 64.1/63.5, CH |
| 13 | 128.6, C | 173.5/171.0, C | 175.8/173.6, C |
| 14 | 110.5, CH | 116.8/117.9, CH | 115.9/116.7, CH |
| 15 | 143.7, CH | 171.0, C | 171.1, C |
| 16 | 140.8, CH | 97.2/98.1, CH | 98.7/98.0, CH |
| 17 | 178.3, C | 179.7, C | 177.7, C |
| 18 | 166.9, C | 166.6, C | 166.8, C |
| 19 | 27.2, CH3 | 27.0, CH3 | 27.3, CH3 |
| 20 | 21.6, CH3 | 20.7/21.5, CH3 | 21.0/21.9, CH3 |
| OMe | 51.6, CH3 | 51.8, CH3 | 52.1, CH3 |
| CH3CO | |||
| CH3 CO | |||
| 1′ | 101.7, CH | ||
| 2′ | 75.6, CH | ||
| 3′ | 78.6, CH | ||
| 4′ | 72.2, CH | ||
| 5′ | 78.2, CH | ||
| 6′ | 63.1, CH2 |
aMeasured in pyridine-d 5 (δ C 149.9 ppm)
bMeasured in CDCl3 (δ C 77.0 ppm)
cMeasured in DMSO-d 6 (δ C 39.5 ppm)