Table 2.

¹H NMR spectroscopic data (600 MHz, pyridine-d₅) for hesperusides A-C (1–3) ¹ (δ in ppm, J in Hz).

Position	1	2	3
1	2.06 m; 1.50 m	2.06 m; 1.50 m	1.52 m; 1.32 m
2	1.85 m; 2.02 m	1.88 m; 2.02 m	1.80 m; 1.21 m
3	4.52 m	4.50 m	4.31 m
4	1.92 m; 2.48 t (14.6, 16.1)	1.92 m; 2.48 t (16.3, 16.3)	1.90 m; 2.31 m
5	2.91 brd (15.0)	2.94 brd (16.2)	2.79 brd (13.0)
6	4.34 m	4.33 m	4.66 m
7	4.96 d (2.2)	4.96 m	3.71 d (2.4)
8
9	2.80 brt (8.9)	2.80 brt (8.6)	2.64 m
10
11	1.75 m; 1.74 m	1.76 m; 1.74 m	1.52 m; 1.62 m
12	1.38 m; 1.86 m	1.48 m; 1.96 m	1.32 m; 1.79 m
13
14
15	3.10 m; 3.21 m	3.06 m; 3.27 m	2.90 m; 3.10 m
16	4.79 m	4.78 m	4.79 m
17	1.72 d (9.9)	1.72 d (9.9)	1.60 dd (9.6, 2.5)
18	1.06 s	1.06 s	0.91 s
19	1.32 s	1.32 s	1.23 s
20	2.57 m	1.76 m	1.71 m
21	1.24 d (7.9)	1.09 d (7.2)	0.78 d (7.0)
22	6.15 m	1.86 m; 1.60 m	1.38 m
23	5.45 m	1.50 m; 1.26 m	1.90 m; 2.31 m
24	2.09 m	1.27 m
25	1.68 m	1.58 m	2.42 m
26	0.96 d (5.1)	0.92 d (7.6)	1.11 d (7.6)
27	0.98 d (5.1)	0.92 d (7.6)	1.11 d (7.6)
28			4.75 s; 4.77 s
MeGalf
1′	5.80 d (3.2)	5.81 d (1.1)	5.61 d (3.2)
2′	4.76 m	4.73 m	4.56 m
3′	4.87 m	4.86 m	4.87 m
4′	4.70 m	4.69 m	4.54 m
5′	4.48 m	4.46 m	4.48 m
6′	4.03 m	4.00 m	3.80 m
6′-OCH3	3.45 s	3.44 s	3.29 s
MeGalp
1′′	4.80 d (7.7)	4.81 d (7.6)	4.70 d (7.7)
2′′	3.94 m	3.93 m	3.94 m
3′′	3.76 t	3.74 t	3.58 t
4′′	4.15 m	4.09 m	4.15 m
5′′	3.89 m	3.89 m	3.89 m
6′′	4.37 m; 4.53 m	4.34 m; 4.53 m	4.32 m; 4.73 m
3′′-OCH3	3.91 s	3.90 s	3.72 s

¹ Assignments aided by ¹H–¹H COSY, TOCSY, HMQC, HMBC, and NOESY experiments.