Chart 5. Products from Trifluoromethylazidation of Natural Productsa.

^a Conditions: 5 (2 equiv), TMSN₃ (1.5 equiv), 10 mol % Fe(OAc)₂, 11 mol % ligand L1, and 0.1 mmol of the substrate in CH₃CN at 23 °C. ^bReaction was conducted in EtOAc. Isolated yields of major CF₃/azide products were reported unless mentioned otherwise. The ratios of isomers were determined by ¹⁹F NMR analysis of the crude reaction mixtures.