Table 4.
Compound | Arbequina 1 | Arbequina 2 | Arauco 1 | Arauco 2 | Changlot | Hojiblanca | Picual | Blend 1 | Blend 2 | Blend 3 | |
---|---|---|---|---|---|---|---|---|---|---|---|
OxHTY | 0.163 ± 0.008 | 1.87 ± 0.09 | 1.91 ± 0.09 | 0.19 ± 0.01 | 0.34 ± 0.02 | 0.122 ± 0.006 | 2.3 ± 0.1 | n.q. | 1.9 ± 0.1 | 0.51 ± 0.02 | |
AcHTY | 1.34 ± 0.07 | 0.47 ± 0.02 | 1.10 ± 0.06 | 0.41 ± 0.02 | n.d. | 0.27 ± 0.01 | 2.9 ± 0.2 | n.d. | 9.2 ± 0.5 | 0.20 ± 0.01 | |
OleAgly | Isomer 1 | 0.74 ± 0.04 | 1.04 ± 0.05 | 2.7 ± 0.1 | 5.4 ± 0.3 | n.d. | n.d. | n.q. | 10.8 ± 0.5 | 1.10 ± 0.06 | 6.1 ± 0.3 |
Isomer 2 | n.d. | n.d. | n.d. | 25 ± 1 | 19.2 ± 0.9 | n.d. | 15.8 ± 0.6 | 115 ± 6 | 48 ± 2 | 43 ± 2 | |
Isomer 3 | 1.50 ± 0.07 | 2.6 ± 0.1 | 11.7 ± 0.6 | 85 ± 4 | 58 ± 3 | 2.1 ± 0.1 | n.q. | 7.8 ± 0.4 | 13.3 ± 0.6 | 3.4 ± 0.2 | |
Isomer 4 | 2.0 ± 0.1 | 2.4 ± 0.2 | 5.5 ± 0.3 | 8.9 ± 0.5 | 3.3 ± 0.2 | 1.46 ± 0.07 | 12.7 ± 0.8 | 10.1 ± 0.5 | n.d. | 3.9 ± 0.2 | |
Main isomer | 12.7 ± 0.6 | 7.5 ± 0.4 | 32 ± 2 | 147 ± 7 | 87 ± 4 | 6.5 ± 0.3 | 36 ± 2 | 24 ± 1 | 28 ± 1 | 11.1 ± 0.6 | |
Isomer 5 | 4.1 ± 0.2 | 3.1 ± 0.1 | 1.16 ± 0.04 | 3.1 ± 0.1 | 2.5 ± 0.1 | 2.6 ± 0.1 | 4.3 ± 0.2 | 19.1 ± 0.8 | 3.7 ± 0.2 | 3.8 ± 0.1 | |
Total | 21.1 ± 0.6 | 16.6 ± 0.4 | 53 ± 2 | 274 ± 8 | 170 ± 5 | 12.8 ± 0.3 | 69 ± 2 | 187 ± 6 | 94 ± 1 | 72 ± 2 | |
DOA | 12.1 ± 0.6 | 23 ± 1 | 11.5 ± 0.6 | 11.8 ± 0.6 | 16.6 ± 0.9 | 5.4 ± 0.2 | 25 ± 1 | 18.4 ± 0.9 | 10.0 ± 0.4 | 11.6 ± 0.6 | |
AcPin | 11.1 ± 0.6 | 2.5 ± 0.1 | 1.21 ± 0.06 | 1.02 ± 0.05 | 3.2 ± 0.1 | 0.82 ± 0.05 | 1.08 ± 0.05 | 3.2 ± 0.1 | 1.52 ± 0.08 | 2.14 ± 0.09 | |
LigAgly | Isomer 1 | 10.6 ± 0.6 | 2.8 ± 0.2 | 10.8 ± 0.6 | 103 ± 6 | 38 ± 2 | 5.9 ± 0.4 | 17 ± 1 | 19 ± 1 | 7.1 ± 0.4 | 4.7 ± 0.2 |
Main isomer | 7.6 ± 0.4 | 18.7 ± 0.9 | 9.6 ± 0.5 | 11.3 ± 0.6 | 10.3 ± 0.5 | 4.4 ± 0.2 | 18.8 ± 0.9 | 36 ± 2 | 6.4 ± 0.3 | 16.2 ± 0.8 | |
Isomer 2 | 6.7 ± 0.3 | n.d. | 5.9 ± 0.3 | 5.1 ± 0.3 | 6.1 ± 0.3 | 5.8 ± 0.3 | 8.4 ± 0.4 | 11.4 ± 0.5 | 16.1 ± 0.8 | n.d. | |
Total | 24.8 ± 0.8 | 21.4 ± 0.9 | 26.2 ± 0.8 | 119 ± 6 | 54 ± 2 | 16.1 ± 0.5 | 44 ± 1 | 67 ± 2 | 30 ± 1 | 20.9 ± 0.8 |
Every result is the average of three independent (sample preparation and injection) determinations (n = 3). The results are given by the mean value ± SD. OxHTY and AcHTY were quantified in terms of HTY; AcPin, by using the calibration curve of Pin; OleAgly and its isomers, DOA, and LigAgly and its two isomers were quantified in terms of Ole. n.d.: non detected; n.q.: non quantified.