Table 4.
Statistical parameters obtained for the PLS-1 regression model established between the chemical parameters and the voltammetric (e-tongue), CIELab and Raman responses towards nalewka liqueurs.
| Voltammetric Outputs | |||||
| Parameters | R2C(a) | RMSEC(b) | R2P(c) | RMSEP(d) | Latent Variables |
| Polyphenolic content (Folin–Ciocalteu method) |
0.976744 | 29.75508 | 0.939679 | 47.74666 | 4 |
| Density | 0.925237 | 0.001112 | 0.878397 | 0.001751 | 4 |
| CIELab Outputs | |||||
| Parameters | R2C(a) | RMSEC(b) | R2P(c) | RMSEP(d) | Latent Variables |
| Polyphenolic content (Folin–Ciocalteu method) |
0.996525 | 8.180929 | 0.994252 | 11.27284 | 3 |
| Density | 0.879691 | 0.001410 | 0.807301 | 0.001912 | 3 |
| Raman Outputs | |||||
| Parameters | R2C(a) | RMSEC(b) | R2P(c) | RMSEP(d) | Latent Variables |
| Polyphenolic content (Folin–Ciocalteu method) |
0.906231 | 42.49629 | 0.793365 | 67.59048 | 6 |
| Density | 0.962399 | 0.000788 | 0.856644 | 0.001650 | 3 |
(a) Squared correlation coefficient in calibration; (b) Root mean square error of calibration; (c) Squared correlation coefficient in prediction; (d) Root mean square error of prediction.