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Structures of the family of six zinc complexes studied as rac‐LA ROP catalysts herein: amido complexes [Zn2 LEt(HMDS)2] 1, [Zn2 LPr(HMDS)2] 2, and [ZnLOpen(HMDS)] 3 and the corresponding alkoxides [Zn2 LEt(OiPr)2] 4,[12] [Zn2 LPr(OiPr)2] 5, and [ZnLOpen(OiPr)2] 6.
