Table 1.
The classification of major processing strategies and corresponding compositions of porous ceramics produced from polysiloxane precursors.
Processing strategy | Composition | Remarks | References |
---|---|---|---|
I. Replica | |||
SiC | Open cells | [57–61, 63] | |
Cell size: >150 μm | |||
Porosity range: 85–96% | |||
SiC–Si3N4 | [57, 59, 60] | ||
SiC–TiC | [57] | ||
SiOC/C | [54] | ||
II. Sacrificial template | |||
SiC | Open cells | [68, 72] | |
Cell size: 10–100 μm | |||
SiOC | Open or closed cells | [69, 70] | |
Cell density: >104 cells cm-3 | |||
Porosity range: 21–80% | |||
Expandable or PMMA templates | SiOC | Open, closed or partially interconnected cells | [67, 73–76] |
Cell size: 0.5–80 μm | |||
Cell density: >109 cells cm-3 | |||
Porosity range: 56–88% | |||
SiC | [17, 77] | ||
Expanded (hollow) templates | SiOC | Closed cells | [66] |
Cell size: <30 μm | |||
Cell density: >109 cells cm-3 | |||
Porosity range: 70–87% | |||
III. Direct foaming | |||
Foaming by chemical agent | SiOC | Open, closed or interconnected cells | [6, 78, 81–85, 87, 139] |
Cell size: 80–800 μm | |||
Porosity range: 75–90% | |||
SiOC + SiC | Open cells | [82] | |
Cell size: 100–700 μm | |||
Foaming using CO2 | |||
Batch process | SiOC | Closed cells | [79, 90, 92, 96] |
Cell size: 2–50 μm | |||
Cell density: 107–1012 cells cm-3 | |||
Porosity: 45% | |||
SiC | [90, 91] | ||
Extrusion process | SiOC | Open or closed cells | [93, 94] |
Cell density: >107 cells cm-3 | |||
Porosity range: 27–90% | |||
IV. Reaction technique | |||
SiC | Open cells | [18, 97–102, 104–106] | |
Cell size: 10–45 μm | |||
Cell density: >109 cells cm-3 | |||
Porosity range: 32–94% | |||
Mullite | Partially interconnected open cells | [107–109 ] | |
Cell size: <20 μm | |||
Cell density: >109 cells cm-3 | |||
Porosity range: 32–85% | |||
Cordierite | Interconnected open cells | [110, 111] | |
Cell size: 13 um | |||
Cell density: 109 cells cm-3 | |||
Porosity range: 11–75% |