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. Author manuscript; available in PMC: 2017 Nov 2.
Published in final edited form as: J Am Chem Soc. 2016 Oct 20;138(43):14210–14213. doi: 10.1021/jacs.6b09333

Table 1.

Enantioselective iridium-catalyzed C-C coupling of 2-substituted dienes 1a–1l with methanol to form neopentyl alcohols 2a–2l.a

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a

Yields of material isolated by silica gel chromatography. Enantioselectivities were determined by chiral stationary phase HPLC analysis. See Supporting Information for further experimental details.

b

Acetone:Methanol (1:1).