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Molecular structure of [Li{N(SiMe3)(Dipp)}(TMEDA)] (6). Thermal ellipsoids are displayed at 35 % probability, hydrogen atoms, and the disordered component of TMEDA ligand and two methyl groups of one iPr unit are omitted for clarity. Selected bond lengths [Å] and angles [°]: Li1−N1 1.905(4); N1−C1 1.388(2); Si1−N1 1.6756(17); Si1‐N1‐Li1 121.50(15); C1‐N1‐Li1 108.20(17); C1‐N1‐Si1 130.30(13).
