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. Author manuscript; available in PMC: 2017 Oct 4.
Published in final edited form as: Angew Chem Int Ed Engl. 2016 Jun 22;55(41):12596–12624. doi: 10.1002/anie.201600547

Scheme 3.

Scheme 3

Lewis acid-promoted, diastereoselective, Schmidt ring-expansion reactions. Blue arrows indicate C–C bond migration. The red dotted line indicates a cation–π interaction.