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. Author manuscript; available in PMC: 2017 Oct 4.
Published in final edited form as: Angew Chem Int Ed Engl. 2016 Jun 22;55(41):12596–12624. doi: 10.1002/anie.201600547

Scheme 16.

Scheme 16

(A) Tetrabutylammonium-templated Norrish-Yang cyclization, and (B) a model for the observed diastereoselectivity. Red dotted lines represent cation–π interactions; blue dotted lines represent other noncovalent interactions.