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. Author manuscript; available in PMC: 2017 Sep 16.
Published in final edited form as: J Org Chem. 2016 Sep 8;81(18):8585–8594. doi: 10.1021/acs.joc.6b01923

Table 5.

Osmium(0) catalyzed coupling of ethyl mandelate 1a with functionalized olefins 2a-2f.a

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a

Yields are of material isolated by silica gel chromatography. See Supporting Information for further experimental details.

b

C10H15CO2H was omitted.

c

Neat.

d

C10H15CO2H (30 mol%)

e

2d (300 mol%).

f

XPhos was omitted.