Table 2.
Membrane | cHEMA (vol%) | Polymerization time (min) | Poly(HEMA) content (%)a | SP content (%)b | FRLc | FUVc | ΔF (%)d |
---|---|---|---|---|---|---|---|
0.2 μm | 0 | 0 | 0 | 0 | 1.6 | -e | – |
0.2 μm | 0.2 | 1200 | 0.38 | -e | 6.2 | 9.3 | 50 |
0.2 μm | 1 | 1200 | 3.2 | -e | 8.9 | 10 | 13 |
0.2 μm | 10 | 15 | 12 | -e | 0.96 | 1.2 | 30 |
0.2 μm | 10 | 60 | 19 | -e | 0f | 1.3 | >103 |
0.2 μm | 10 | 120 | 25 | 3.2 | -e | -e | – |
0.2 μm | 10 | 240 | 28 | -e | 0f | 0.11 | >103 |
0.2 μm | 10 | 1200 | 31 | -e | 0.031 | 0.19 | 530 |
0.2 μm | 25 | 1200 | 48 | 3.5 | 0.41 | 0.49 | 20 |
1 μm | 0 | 0 | 0 | 0 | 40 | -e | – |
1 μm | 10 | 1200 | 17 | 5.7 | 4.8 | 6.1 | 27 |
1 μm | 25 | 1200 | 31 | 8.8 | 0.21 | 0.34 | 62 |
2 μm | 0 | 0 | 0 | 0 | 39 | -e | – |
2 μm | 10 | 1200 | 4.9 | 3.9 | 9.0 | 14 | 56 |
2 μm | 25 | 1200 | 7.2 | 3.5 | 1.4 | 1.6 | 14 |
Determined by measuring the average membrane mass before and after polymerization.
Determined by decomposing of the spiropyran in the membrane and measuring the concentration of 2-hydroxy-5-nitrobenzaldehyde (decomposition product).
Units: 10−9 mol s−1 cm−2.
ΔF = 100 (FUV − FRL)/FRL.
Was not determined.
Permeability below detection limit.