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ATR-IR spectra of adsorbed a) mfp3S-pep, b) mfp3S-pep-3Dopa, and c) mfp3S-pep-3Dopa coacervate on TiO2 from 0.1 mg mL−1 solutions recorded at ≈2 min intervals. Backgrounds were from (a) and (b) 100 × 10−3m acetic acid and (c) buffer at pH 6.5 on TiO2-coated ZnSe prism.