Table 2.

Photoredox-Enabled Csp³–Csp² Coupling from Alkyl and Aryl Halide Precursors: Comprehensive Scope of Products^a

^aAll yields are isolated yields using photocatalyst 1 (1 mol %), NiCl₂·dtbbpy (0.5 mol %), aryl halide (0.5 mmol), alkyl halide (0.75 mmol), TTMSS

(0.5 mmol), and Na₂CO₃ (2 equiv).

^b12 h

^cLiOH as base.

^dAryl chloride.

^e10 mol % 2.

^f5 mol % 2.

^gMOMCl.

^hMeOTs and LiBr.

ⁱDioxane as solvent.

^j48 h.

^k24 h.