Table 3. Monophasic models, kinetic parameters and statistical indices in the prediction of radical scavenging activity of pumpkin seed oil.
Model/parameter | Oil sample | ||||||||
---|---|---|---|---|---|---|---|---|---|
CP1 | CP2 | RS1 | RS2 | RS3 | RS4 | RS5 | S1 | S2 | |
Zero-order model | |||||||||
k0 | –0.029 | –0.030 | –0.018 | –0.025 | –0.025 | –0.020 | –0.019 | –0.027 | –0.031 |
R2 | 0.9792 | 0.9563 | 0.9593 | 0.9816 | 0.9642 | 0.9723 | 0.9654 | 0.9138 | 0.9443 |
SRMSE | 0.144 | 0.221 | 0.200 | 0.134 | 0.190 | 0.164 | 0.185 | 0.311 | 0.251 |
χ2 error | 11.96 | 18.57 | 16.62 | 11.15 | 15.78 | 13.62 | 15.47 | 25.79 | 20.94 |
First-order model | |||||||||
k1 | 0.062 | 0.081 | 0.044 | 0.050 | 0.058 | 0.043 | 0.043 | 0.097 | 0.090 |
R2 | 0.9912 | 0.9832 | 0.9663 | 0.9892 | 0.9773 | 0.9792 | 0.9724 | 0.9564 | 0.9764 |
SRMSE | 0.094 | 0.137 | 0.182 | 0.103 | 0.151 | 0.142 | 0.165 | 0.221 | 0.163 |
χ2 error | 7.79 | 11.51 | 15.13 | 8.54 | 12.57 | 11.81 | 13.81 | 18.34 | 13.62 |
Logarithmic model | |||||||||
k1 | 0.188 | 0.224 | 0.833 | 0.236 | 0.344 | 0.412 | 0.504 | 0.369 | 0.255 |
R2 | 0.9996 | 0.9997 | 0.9923 | 0.9995 | 0.9986 | 0.9994 | 0.9986 | 0.9996 | 0.9983 |
SRMSE | 0.019 | 0.019 | 0.084 | 0.022 | 0.036 | 0.024 | 0.036 | 0.021 | 0.043 |
χ2 error | 1.60 | 1.65 | 7.17 | 1.90 | 3.09 | 2.04 | 3.07 | 1.79 | 3.66 |
k0 and k1=rate constants, R2=determination coefficient, SRMSE=scaled root mean square error, χ2 error=error of chi-square test. For oil sample abbreviations see Table 1