Table 4. Biphasic models, kinetic parameters and statistical indices in the prediction of radical scavenging activity of pumpkin seed oil.
Model/parameter | Oil sample | ||||||||
---|---|---|---|---|---|---|---|---|---|
CP1 | CP2 | RS1 | RS2 | RS3 | RS4 | RS5 | S1 | S2 | |
Weibull distribution model | |||||||||
kα | 4.054 | 2.629 | 0.813 | 4.479 | 2.370 | 2.907 | 1.866 | 1.863 | 2.668 |
β | –0.550 | –0.606 | –0.249 | –0.436 | –0.413 | –0.333 | –0.311 | –0.627 | –0.685 |
R2 | 0.9999 | 0.9995 | 0.9999 | 0.9998 | 0.9994 | 0.9986 | 0.9984 | 0.9947 | 0.9983 |
SRMSE | 0.012 | 0.023 | 0.006 | 0.014 | 0.025 | 0.036 | 0.039 | 0.077 | 0.001 |
χ2 error | 0.96 | 1.93 | 0.47 | 1.17 | 2.08 | 2.97 | 3.28 | 6.37 | 0.03 |
First-order double-exponential model | |||||||||
k1 | 0.067 | 0.417 | 3.671 | 0.484 | 0.866 | 0.953 | 0.239 | 0.431 | 0.356 |
k2 | 0.307 | 0.131 | 0.186 | 0.094 | 0.160 | 0.217 | 1.302 | 0.072 | 0.069 |
R2 | 0.9999 | 0.9999 | 0.9999 | 0.9995 | 0.9997 | 0.9999 | 0.9999 | 0.9999 | 0.9988 |
SRMSE | 0.008 | 0.003 | 0.008 | 0.022 | 0.018 | 0.003 | 0.009 | 0.011 | 0.037 |
χ2 error | 0.73 | 0.27 | 0.73 | 1.96 | 1.62 | 0.28 | 0.82 | 0.97 | 3.34 |
Gustafson and Holden model | |||||||||
kα | 0.564 | 0.651 | 0.175 | 0.336 | 0.315 | 0.226 | 0.216 | 0.536 | 0.705 |
β | 3.207 | 2.580 | 0.065 | 1.423 | 0.675 | 0.399 | 0.238 | 1.146 | 2.554 |
R2 | 0.9998 | 0.9996 | 0.9999 | 0.9998 | 0.9954 | 0.9992 | 0.9990 | 0.9966 | 0.9973 |
SRMSE | 0.015 | 0.012 | 0.010 | 0.070 | 0.021 | 0.028 | 0.030 | 0.060 | 0.054 |
χ2 error | 1.30 | 1.70 | 0.84 | 5.94 | 1.77 | 2.34 | 2.56 | 5.08 | 4.59 |
k1 and k2=rate constants, kα and β=shape and location parameters, R2=determination coefficient, SRMSE=scaled root mean square error, χ2 error=error of chi-square test. For oil sample abbreviations see Table 1