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. 2016 Jun;54(2):200–210. doi: 10.17113/ftb.54.02.16.4063

Table 4. Biphasic models, kinetic parameters and statistical indices in the prediction of radical scavenging activity of pumpkin seed oil.

Model/parameter Oil sample
CP1 CP2 RS1 RS2 RS3 RS4 RS5 S1 S2
Weibull distribution model
kα 4.054 2.629 0.813 4.479 2.370 2.907 1.866 1.863 2.668
β –0.550 –0.606 –0.249 –0.436 –0.413 –0.333 –0.311 –0.627 –0.685
R2 0.9999 0.9995 0.9999 0.9998 0.9994 0.9986 0.9984 0.9947 0.9983
SRMSE 0.012 0.023 0.006 0.014 0.025 0.036 0.039 0.077 0.001
χ2 error 0.96 1.93 0.47 1.17 2.08 2.97 3.28 6.37 0.03
First-order double-exponential model
k1 0.067 0.417 3.671 0.484 0.866 0.953 0.239 0.431 0.356
k2 0.307 0.131 0.186 0.094 0.160 0.217 1.302 0.072 0.069
R2 0.9999 0.9999 0.9999 0.9995 0.9997 0.9999 0.9999 0.9999 0.9988
SRMSE 0.008 0.003 0.008 0.022 0.018 0.003 0.009 0.011 0.037
χ2 error 0.73 0.27 0.73 1.96 1.62 0.28 0.82 0.97 3.34
Gustafson and Holden model
kα 0.564 0.651 0.175 0.336 0.315 0.226 0.216 0.536 0.705
β 3.207 2.580 0.065 1.423 0.675 0.399 0.238 1.146 2.554
R2 0.9998 0.9996 0.9999 0.9998 0.9954 0.9992 0.9990 0.9966 0.9973
SRMSE 0.015 0.012 0.010 0.070 0.021 0.028 0.030 0.060 0.054
χ2 error 1.30 1.70 0.84 5.94 1.77 2.34 2.56 5.08 4.59

k1 and k2=rate constants, kα and β=shape and location parameters, R2=determination coefficient, SRMSE=scaled root mean square error, χ2 error=error of chi-square test. For oil sample abbreviations see Table 1