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A) The ECL spectra of HRP-MB-MCH-BP-AuNPs-Th-RGO-GCE in presence of 0.5 mM luminol + 2 mM H2O2 in the absence and presence of applying CV and cleavage with active caspase-3 protein; B) The CEL spectra of HRP-MB-MCH-BP-AuNPs-Th-RGO-GCE in PBS (pH=9.5), PBS (pH=9.5)+0.45 mM luminol, and PBS (pH=9.5)+0.45 mM luminol+2 mM H2O2.
