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. Author manuscript; available in PMC: 2017 Aug 22.
Published in final edited form as: ChemCatChem. 2016 Jul 26;8(16):2609–2613. doi: 10.1002/cctc.201600487

Figure 1.

Figure 1

Catalytic activity of various hemoproteins in the oxidative deamination of benzyl azide 1 to benzaldehyde 2a (a). (b-c) Reactions (400 μL) were conducted under anaerobic conditions with 10 mM BnN3, 10 mM Na2S2O4, and 1 μM protein for 24 hours at room temperature. TON = nmol aldehyde / nmol catalyst. Product yield is based on conversion of 1 to 2a as determined by gas chromatography. (d) Reaction rates as determined over the first 10 minutes of the reaction. (e) TON vs. pH plot for FL#62 reaction.