. Author manuscript; available in PMC: 2016 Nov 17.

Published in final edited form as: Macromolecules. 2016 Feb 2;49(4):1191–1200. doi: 10.1021/acs.macromol.6b00137

Table 3.

Functional Group (FG) Ratios of Three Different Monomers (AZ-2, AL-1, and AL-4) Used To Create an Off-Stoichiometric Resin with Excess Azide Functionality with the Resulting Azide Conversions and Material Properties Including T_g and Molecular Weight between Cross-Links (M_c) As Calculated from Rubber Elasticity Included

AZ-2 monomer (FG eq)	AL-4 monomer (FG eq)	AL-1 monomer (FG eq)	theor azide conv (%)	measd azide conv (%)	T_g (°C)	M_c (g/mol)
1 eq	0.5 eq alk	0.25 eq alk	75	74	46	~85000
1 eq	0.4 eq alk	0.4 eq alk	80	83	51	~20000
1 eq	0.2 eq alk	0.7 eq alk	90	91	59	~9000
1 eq	0 eq alk	1 eq alk	100	~99	67	~1600