Table 1. Photophysical properties of the compounds.
| Compounds | λema (nm) | ФFb (%) | ФFc (%) | τe (ns) | τf (ns) |
|---|---|---|---|---|---|
| PyCl | 486 | 2.5 | 0.2 | 0.14 | 2.71 |
| PyNO3 | 467 | 10.4 | 0.3 | 0.26 | 1.85 |
| PyOTs | 448 | 13.1 | 0.1 | 0.16 | 7.81 |
| PyPh4B | — | <1 | — | 0.11 | 0.1 |
aEmission wavelength in the solid state.
bAbsolute fluorescence quantum yields of solids determined by a calibrated integrating sphere.
cAbsolute fluorescence quantum yields in acetonitrile of compounds determined by a calibrated integrating sphere.
dFluorescence lifetimes in acetonitrile.
eFluorescence lifetimes of the solid samples.