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. Author manuscript; available in PMC: 2017 Jan 1.
Published in final edited form as: J Biomater Sci Polym Ed. 2016 Oct 19;28(1):15–32. doi: 10.1080/09205063.2016.1239947

Table 2.

Surface elemental concentrations for DC-TMS + NH3/O2 over 12-week immersion period from XPS (atomic %)

Immersion time C Si O N Na Cl Al Zn K P Ti Fe N/Si*
Day 0 16.54 21.38 59.54 2.41 0.13 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.11
Day 1 23.90 18.15 52.59 2.63 1.69 0.00 1.04 0.00 0.00 0.00 0.00 0.00 0.14
Day 3 22.58 15.72 51.98 1.68 5.05 1.27 0.63 0.12 0.45 0.52 0.00 0.00 0.11
Week 1 28.83 12.84 44.58 1.21 6.59 2.15 0.85 0.00 1.24 1.64 0.07 0.00 0.09
Week 2 44.77 16.45 33.26 1.76 2.23 1.27 0.00 0.00 0.00 0.00 0.00 0.26 0.11
Week 4 46.75 19.36 31.24 1.68 0.97 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.09
Week 12 49.18 19.17 30.31 1.34 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.07
*

denotes ratio of N-to-Si within surface region