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. 2016 Nov 25;10:71. doi: 10.1186/s13065-016-0218-4

Table 1.

Electronic, emission spectral data of complexes 14 in H2O at 25 °C

Complex UV visible absorption/nm Excitation/nm Emission/nm
Inter-ligand MLCT
w[Re(CO)3L1(H2O)]+ (1) 330 420 425 700
a[Re(CO)3L1(H2O)]+ (1) 470 710
wRe(CO)3L1Br (2) 328 400 400 480b, 658
w[Re(CO)3L2(H2O)]+ (3) 315 395 441 672
a[Re(CO)3L2(H2O)]+ (3) 424 645
wRe(CO)3L2Br (4) 300 396 398 640
aRe(CO)3L2Br (4) 396 645

WIn water

aIn acetonitrile

bPeak due to excess ligand