Table 1.
Electronic, emission spectral data of complexes 1–4 in H2O at 25 °C
Complex | UV visible absorption/nm | Excitation/nm | Emission/nm | |
---|---|---|---|---|
Inter-ligand | MLCT | |||
w[Re(CO)3L1(H2O)]+ (1) | 330 | 420 | 425 | 700 |
a[Re(CO)3L1(H2O)]+ (1) | 470 | 710 | ||
wRe(CO)3L1Br (2) | 328 | 400 | 400 | 480b, 658 |
w[Re(CO)3L2(H2O)]+ (3) | 315 | 395 | 441 | 672 |
a[Re(CO)3L2(H2O)]+ (3) | 424 | 645 | ||
wRe(CO)3L2Br (4) | 300 | 396 | 398 | 640 |
aRe(CO)3L2Br (4) | 396 | 645 |
WIn water
aIn acetonitrile
bPeak due to excess ligand