Table 5.
Selectivity testing results for 80Se+ in the presence of interfering species.
| Spectral interference for80Se+ | Highest anticipated conc. in human whole blood |
Interference concentration |
Se recovery in spiked base blood¥ |
Se recovery in low QC pool¥ |
Se recovery in spiked QMEQAS07B0-09¥ |
|---|---|---|---|---|---|
| 64Ni16O+ | 0.028 mg L−1 Ni [50] | 0.300 mg L−1 Ni | 98% | 96% | 100% |
| 64Ni12C1H4+ | |||||
| 48Ti16O2+ | 0.150 mg L−1 Tia | 1.5 mg L−1 Ti | 100% | 95% | 100% |
| 48Ti(12C1H4)2+ | |||||
| 63MCu17O+ | 1.5 mg L−1 Cu [50] | 15 mg L−1 Cu | 99% | 94% | 102% |
| 64Zn16O+ | 7.18 mg L−1 Znb | 7 mg L−1 Zn | 101% | 95% | 100% |
| 64Zn12C1H4+ | |||||
| 40Ca40Ar+ | 86–100 mg L−1 Ca in serum [50] | 500 mg L−1 Ca | 102% | 97% | 102% |
| 40K40Ar+ | 200 mg L−1 Kc | 200 mg L−1 K | 101% | 97% | 102% |
Calculated from upper value of 0.15 mg/kg (ppm) [52].
Value calculated from reference of 1.22 μg/mL Zn in plasma and plasma containing 17% of the total Zn in whole blood [53].
See Table 4.
Results calculated relative to unspiked base blood, QC, or CTQ reference material. Average measured Se concentration in base blood was 268 μg L−1. Average measured Se concentration in low QC pool was 215 μg L−1. Average measured Se concentration in QMEQAS07B-09 was 169 μg L−1.