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. Author manuscript; available in PMC: 2018 Jan 1.
Published in final edited form as: Talanta. 2016 Sep 28;162:114–122. doi: 10.1016/j.talanta.2016.09.060

Table 5.

Selectivity testing results for 80Se+ in the presence of interfering species.

Spectral interference for80Se+ Highest anticipated conc. in
human whole blood
Interference
concentration
Se recovery in spiked
base blood¥
Se recovery in low
QC pool¥
Se recovery in spiked
QMEQAS07B0-09¥
64Ni16O+ 0.028 mg L−1 Ni [50] 0.300 mg L−1 Ni 98% 96% 100%
64Ni12C1H4+
48Ti16O2+ 0.150 mg L−1 Tia 1.5 mg L−1 Ti 100% 95% 100%
48Ti(12C1H4)2+
63MCu17O+ 1.5 mg L−1 Cu [50] 15 mg L−1 Cu 99% 94% 102%
64Zn16O+ 7.18 mg L−1 Znb 7 mg L−1 Zn 101% 95% 100%
64Zn12C1H4+
40Ca40Ar+ 86–100 mg L−1 Ca in serum [50] 500 mg L−1 Ca 102% 97% 102%
40K40Ar+ 200 mg L−1 Kc 200 mg L−1 K 101% 97% 102%
a

Calculated from upper value of 0.15 mg/kg (ppm) [52].

b

Value calculated from reference of 1.22 μg/mL Zn in plasma and plasma containing 17% of the total Zn in whole blood [53].

c

See Table 4.

¥

Results calculated relative to unspiked base blood, QC, or CTQ reference material. Average measured Se concentration in base blood was 268 μg L−1. Average measured Se concentration in low QC pool was 215 μg L−1. Average measured Se concentration in QMEQAS07B-09 was 169 μg L−1.