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Schematic illustration of the adhesion of Mfp‐3 and 5 in the presence of Mfp‐6. Oxidation of catechol (A) and the formation of dithiol bonds (B) in Mfp‐6 counteract the autoxidation of catechol in Mfp‐3/5 to quinone to enhance the adsorption of Mfp‐3/5 to the substrate surface (C, D). Reprinted by permission from Macmillan Publishers Ltd: Nature Chemical Biology Ref. 102, copyright 2011.
