Table 1.
NMR Spectroscopic data for acthaside
| Position | Isolated compound (acthaside) | |
|---|---|---|
| δH (J in Hz) | δC, type | |
| 1 | - | - |
| 2 | - | 166.7, C |
| 3 | 5.94, (d, 0.7) | 111.6, CH |
| 4 | - | 181.7, C |
| 4a | - | 115.3, C |
| 5 | - | 144.0, C |
| 6 | 6.65 (d, 2.4) | 119.8, CH |
| 7 | - | 161.8, C |
| 8 | 6.62 (d, 2.4) | 102.6, CH |
| 8a | - | 163.1, C |
| 9 | 2.97 (dd, 12.1, 7.4) 3.68 (dd, 12.1, 5.3) |
43.3, CH2 |
| 10 | 4.06 (m) | 76.9, CH |
| 11 | 1.09 (d, 6.2) | 21.5, CH3 |
| 12 | 2.25 (d, 0.7) | 19.9, CH3 |
| 1′ | 4.45 (d, 8.0) | 103.0, CH |
| 2′ | 3.07 (dd, 8.7, 8.0) | 75.5, CH |
| 3′ | 3.27 (m) | 78.3, CH |
| 4′ | 3.20 (m) | 71.9, CH |
| 5′ | 3.21 (m) | 77.9, CH |
| 6′ | 3.58 (m) 3.75 (dd, 11.8, 1.6) |
62.9, CH2 |