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(a) Reversibility reaction scheme. (b) 1H NMR spectrum of a 1.0 mM solution of 1 in 10% DMSO-d6/CD3CN. (c) Treatment with 2 equiv. of NBu4SH. (d) Addition of 4 equiv. Zn(OAc)2. Each inset shows the 13C{1H} resonances corresponding to the alkyne region of 1.