Figure 1. Stepwise design of the pacs-MOF platform.
(a) Anionic framework of Mg3-MIL-88 with the charge-balancing [(CH3)2NH2] cations simplified as blue balls. (b) V3+-containing neutral framework of Mg2V-MIL-88. (c) Pore space partition through TPT insertion in Mg2V-DHBDC. (d) Polyhedral drawing of PSP through TPT insertion in Mg3-DHBDC. TPT=2,4,6-tri(4-pyridinyl)-1,3,5-triazine.