Table 4.

Calculated values of kinetic parameters of linseed oils oxidation based on PDSCτ_max

Parameter	Calculation based on PDSCτmax
	LO1	LO2	LO3	LO4	LO5
Equation 1
−a	0.0342	0.0339	0.0342	0.0341	0.0337
B	5.4517	5.4314	5.4729	5.4735	5.4157
R2	0.9988	0.9983	0.9991	0.9998	0.9996
Equation 2
A	5.1309	5.0896	5.1228	5.1132	5.0550
−B	11.7310	11.6080	11.6820	11.6470	11.5100
R2	0.9957	0.9982	0.9966	0.9986	0.9980
*Ea	94.53	93.77	94.39	94.21	93.14
Z†	5.38 × 1011	4.06 × 1011	4.81 × 1011	4.44 × 1011	3.24 × 1011
k† at 140 °C	0.6010	0.5659	0.5597	0.5445	0.7434
k† at 130 °C	0.3037	0.2875	0.2831	0.2757	0.3794
k† at 120 °C	0.1482	0.1411	0.1383	0.1349	0.1871
k† at 110 °C	0.0697	0.0667	0.0651	0.0636	0.0890
k† at 100 °C	0.0315	0.0303	0.0294	0.0288	0.0406
k† at 90 °C	0.0136	0.0132	0.0127	0.0125	0.0178
Q10	2.13	2.12	2.13	2.13	2.11
*ΔH++	91.3	90.54	91.16	90.98	91.94
**ΔS++	−30.9	−33.2	−31.8	−32.4	−27.3

^† Z and k from Rancimat in h⁻¹ from PDSC in min⁻¹

^* Ea, ΔH in kJ mol⁻¹

^** ΔS in J mol K⁻¹