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. 2016 Nov 29;3(12):1600302. doi: 10.1002/advs.201600302

Table 1.

Comparison of (Mn2+/Yb3+) polyhedral bridging geometry, Mn2+–Yb3+ distance, Mn–L–Yb angle (L = halogen ions) and UC efficiency (ratio of the Mn2+ UC emission to the Yb3+ NIR emission was used when a 191 mW laser beam was focused on the sample by an f = 53 mm lens)33

Compound Bridging geometry Mn2+–Yb3+ distance[Å] Mn–L–Yb angle[°] ηUC[%] T[K] Ref.
Rb2MnCl4:Yb3+ corner 5.05 180 28(site A) 35 34
Rb2MnCl4:Yb3+ corner 5.05 180 18(site B) 15 34
CsMnCl3:Yb3+ corner 5.2 177.2 8.5 75 35
RbMnCl3:Yb3+ corner 5.02 177.1 2 10 32
MnCl2:Yb3+ edge 3.71 92.8 4.1 12 33
MnBr2:Yb3+ edge 3.82 89.8 1.2 12 33
RbMnCl3:Yb3+ face 3.2 77.9 0.02 10 32
CsMnBr3:Yb3+ face 3.26 74.8 0.05 12 36
RbMnBr3:Yb3+ face 3.37 76.1 0.05 12 33