Table 1.
Comparison of (Mn2+/Yb3+) polyhedral bridging geometry, Mn2+–Yb3+ distance, Mn–L–Yb angle (L = halogen ions) and UC efficiency (ratio of the Mn2+ UC emission to the Yb3+ NIR emission was used when a 191 mW laser beam was focused on the sample by an f = 53 mm lens)33
Compound | Bridging geometry | Mn2+–Yb3+ distance[Å] | Mn–L–Yb angle[°] | ηUC[%] | T[K] | Ref. |
---|---|---|---|---|---|---|
Rb2MnCl4:Yb3+ | corner | 5.05 | 180 | 28(site A) | 35 | 34 |
Rb2MnCl4:Yb3+ | corner | 5.05 | 180 | 18(site B) | 15 | 34 |
CsMnCl3:Yb3+ | corner | 5.2 | 177.2 | 8.5 | 75 | 35 |
RbMnCl3:Yb3+ | corner | 5.02 | 177.1 | 2 | 10 | 32 |
MnCl2:Yb3+ | edge | 3.71 | 92.8 | 4.1 | 12 | 33 |
MnBr2:Yb3+ | edge | 3.82 | 89.8 | 1.2 | 12 | 33 |
RbMnCl3:Yb3+ | face | 3.2 | 77.9 | 0.02 | 10 | 32 |
CsMnBr3:Yb3+ | face | 3.26 | 74.8 | 0.05 | 12 | 36 |
RbMnBr3:Yb3+ | face | 3.37 | 76.1 | 0.05 | 12 | 33 |