Table 2. Compounds emitted by D. cf. concentrica.
Retention time (min) | Suggested compound* | Molecular formula | Main fragments (m/z) | Area (%) | MW |
---|---|---|---|---|---|
2.2 | 3-methyl-1-butanol | C5H12O | 42, 55, 57, 70 | 1.0 | 88 |
2.25 | 2-methyl-1-butanol | C5H12O | 41, 56, 57, 70 | 1.1 | 88 |
2.7 | 1-methyl-1,3-cyclohexadiene | C7H10 | 77, 79, 91, 94 | 6.5 | 94 |
2.8 | 1-methyl-1,4-cyclohexadiene | C7H10 | 77, 79, 91, 94 | 3.9 | 94 |
4.1 | 4-heptanone | C7H14O | 43, 71, 114 | 0.2 | 114 |
4.3 | isoamyl acetate | C7H14O2 | traces | 130 | |
5.2 | 4-heptyn-2-ol | C7H12O | 45, 53, 67 68, 97, 112 | 4.2 | 112 |
5.5 | 2-octenal | C8H14O | 42, 55, 57 84, 98, 126 | 33.3 | 126 |
6.3 | octanal | C8H16O | 69, 71, 72 83, 84, 95 110, 128 | 4.7 | 128 |
7.2 | 4,4-dimethyl-1,3-cyclopentanedione | C7H10O2 | 41, 56, 126 | 4.0 | 126 |
7.7 | 2,2,5-trimethylcyclopentanone | C8H14O | 41, 56, 126 | 16.5 | 126 |
10.5 | phenyl ethyl alcohol | C8H10O | 65, 91, 92, 122 | 1.9 | 122 |
18.2 | β-elemene | C15H24 | 41, 53, 55, 67, 68, 79, 81, 93, 107, 121, 133, 135, 147, 149, 161, 189, 204 | 0.06 | 204 |
18.4 | β-elemene | C15H24 | 41, 53, 55, 67, 68, 79, 81, 93, 107, 121, 133, 135, 147, 149, 161, 189, 204 | 1.0 | 204 |
19.4 | (+)-α-funebrene | C15H24 | - | traces | - |
19.6 | α-guaiene | C15H24 | 41, 53, 55, 67, 79, 81, 93, 105, 121, 133, 147, 161, 189, 204 | 0.1 | 204 |
19.9 | 2-(4-hydroxyphenyl)ethanol | C8H10O2 | ? | 0.08 | 204 |
20.7 | terpenes | C10H10O3 | 108, 136, 137, 163, 178 | 9.0 | 178 |
21.0 | β-selinene | C15H24 | 41, 53, 55, 67, 79, 81, 91, 93, 107, 121, 133, 147, 161, 175, 189, 204 | 0.7 | 204 |
21.2 | α-selinene | C15H24 | 41, 53, 55, 67, 79, 81, 91, 93, 107, 121, 133, 147, 161, 175, 189, 204 | 0.2 | 204 |
21.4 | α-bulnesene | C15H24 | 41, 53, 55, 67, 79, 81, 91, 93, 107, 121, 133, 147, 161, 189, 204 | 0.7 | 204 |
21.6 | germacrene A | C15H24 | - | traces | - |
21.8 | 7-epi-α-selinene | C15H24 | - | traces | - |
22.0 | dauca-4(11),8-diene | C15H24 | - | traces | - |
22.9 | veratryl acetone | C11H14O3 | - | traces | - |
25.1 | 3-methoxy-2-naphthol | C11H10O2 | 77, 131, 159, 174 | 1.6 | 174 |
25.2 | pogostol | C15 H26O | 41, 53, 55, 71, 81, 93, 107, 121, 131, 147, 161, 189, 204 | 1.2 | 222 |
* identified according to NIST Mass Spectral Library, ver. 2.0 d