Table 2. Quantification of the pressure influence on ν1-CO32− Raman shift in three Na2CO3-NaCl solutions.
| [Na2CO3] | [NaCl] | Fitting equation (P = aΔν1066 + b) |
R2 | Standard error | |
|---|---|---|---|---|---|
| mol·L−1 | mol·L−1 | Slope (MPa/cm−1) | Intercept (MPa) | MPa | |
| 2.01 | 0.20 | 185(6) | 29(27) | 0.988 | 14 |
| 2.00 | 0.42 | 187(4) | 44(19) | 0.993 | 11 |
| 1.99 | 0.92 | 185(8) | 92(36) | 0.978 | 18 |
P is pressure in MPa. Δν1066 is the relative ν1-CO32− Raman shift under pressure, and its value is between 0 and 10 cm−1. The numbers in the brackets indicate the standard deviations (2σ) for the slope and the intercept. The standard errors (MPa) are calculated with the data in Table 1 and the fitting equations in Table 2.