Table 3. Quantification of the ionic strength influence on ν 1 -CO3 2− Raman shift at ambient conditions based on previous references.
| Sources | [CO32−] | [Cl−] | ∂ν/∂I | R2 | Standard error |
|---|---|---|---|---|---|
| mol·L−1 | mol·L−1 | cm−1 | |||
| Oliver and Davis19 | 1.0−8.0a | 0 | −0.24 | 0.987 | n.d. |
| Sun and Qin30 | 0.768−5.12a | 0 | −0.181 | 0.998 | n.d. |
| 0.741 −1.56b | 0 | −0.063 | 0.993 | 0.033 | |
| 1.0b | 0.5−2.0 | −0.167 | 0.95 | 0.041 | |
| Sipos et al.20 | 0.1b | 0.713−7.68* | −0.044I–0.058 | 0.996 | n.d. |
| 0.1b | <4.7 | ~ −0.113 | n.d. | n.d. |
aPotassium carbonate solution.
bSodium carbonate solution.
*Chloride anion is replaced by hydroxyl anion; n.d. indicates that the value is “not determined”.