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Plot of kX/kD versus χD for the reaction between Q and trans-[OsIV(tpy)(Cl)2(N(H)N(CH2)4O)]PF6 in 1:1 (vol/vol) CH3CN/H2O–D2O mixtures at 25.0 ± 0.1°Cat[Q] < 2.80 × 10–3 M.