Table.
Residue | H1 | H2 | H3 | H4 | H5 | H6 |
---|---|---|---|---|---|---|
C1 | C2 | C3 | C4 | C5 | C6 | |
A | 5.54 | 3.87 | 3.97 | 4.46 | 4.28 | - |
4-α-D-GalpA6LAla(D) | 100.9 | 69.0 | 69.8 | 77.9 | 72.0 | 170.2 |
B | 4.98 | 3.63 | 3.95 | 4.30 | 4.90 | - |
4-α-D-GalpA6LAla(E) | 100.8 | 69.6 | 70.7 | 79.4 | 73.0 | 171.0 |
C | 4.56 | 3.74 | 3.72 | 3.39 | 3.37 | 1.27 |
3-β-D-QuipNAc | 103.5 | 56.0 | 81.2 | 77.7 | 72.5 | 18.4 |
Additional chemical shifts:
NAc: at δ 1.91/24.0 (CH3), 175.9 (CO)
Ala (D): at δ 4.23/52.0 (CH), 1.39/19.2 (CH3), 180.3 (COOH), 7.91 (NH, H2O/D2O)
Ala (E): at δ 4.22/52.2 (CH), 1.42/19.2 (CH3), 181.2 (COOH), 7.70 (NH, H2O/D2O)