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. Author manuscript; available in PMC: 2016 Dec 21.
Published in final edited form as: Adv Exp Med Biol. 2015;851:209–228. doi: 10.1007/978-3-319-16009-2_8

Table 3.2.1.

Conversion rates of gaseous molecules by P450BM3 in the presence of PFCs [29, 30].

Substrate PFCa Rateb (mināˆ’1) Regioselectivity Refs.
Methane C10 2472 [29]
Propane C11
C10
1021
67
[29]
[30]
Butane C7
C10
3632
113
[29]
[30]
Hexane C11 525 2-/3-hexanol = 77:23 [29]
Octane C9 1184 2-/3-/4-octanol = 10:42:48 [29]
Cyclohexane C9 110 [30]
3-Methylpentane C9 476 2-/3-hydroxy = 88:12 [29]
3,3-Dimethylbutane C9 891 Only 2-hydroxy [29]
2,3-Dimethylbutane C11 3241 Only 2-hydroxy [29]
a

Optimal perfluorinated carboxylic acid reported.

b

Observed turnover rates.