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. Author manuscript; available in PMC: 2016 Dec 21.
Published in final edited form as: Bioorg Med Chem. 2014 Jun 25;22(20):5547–5554. doi: 10.1016/j.bmc.2014.06.034

Table 2.

Conversion rates of gaseous molecules by P450BM3 in the presence of PFCs.

Substrate PFCa Rateb (min−1) Regioselectivity Refs.
graphic file with name nihms6370t17.jpg C11 1021 30
graphic file with name nihms6370t17.jpg C10 67 31
graphic file with name nihms6370t18.jpg C7 3632 30
graphic file with name nihms6370t18.jpg C10 113 31
graphic file with name nihms6370t19.jpg C11 525 2-/3-hexanol = 77:23 30
graphic file with name nihms6370t20.jpg C9 1184 2-/3-/4-octanol = 10:42:48 30
graphic file with name nihms6370t21.jpg C9 110 31
graphic file with name nihms6370t22.jpg C9 476 2-/3-hydroxy = 88:12 30
graphic file with name nihms6370t23.jpg C9 891 Only 2-hydroxy 30
graphic file with name nihms6370t24.jpg C11 3241 Only 2-hydroxy 30
a

Optimal perfluorinated carboxylic acid reported.

b

Observed turnover rates.