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A. Schematic of the Ti-O-Mn complex on a mesoporous silica substrate B. Structure of a Ti-O-Mn bridged complex. C. Proposed energy level diagram for the photo-induced metal-to-metal charge transfer (MMCT) processes that determine photocatalytic yields for the TiOMnII charge transfer unit. kBET1 and kISC are ultrafast, kBET2 is the 1.8 μs process.
