Table I.

GC-MS data of metabolites obtained from tomato cell free conversion experiments

Substrate	Metabolite	RRtd	Prominent Ions
		min	m/z, relative intensity %
CHRa	CHRa	0.456	460(M+, 54), 445(73), 370(28), 355(43), 305(33), 215(100)
6-deoxo-28-norTEb	6-deoxo-28-nor-3-DHTb	0.615	442(M+, 73), 427(10), 246(12), 231(100), 217(23), 163(20), 141(15)
	6-deoxo-28-norTYc	0.523	516(M+, 23), 501(6), 459(4), 426(62), 411(60), 305(11), 230(30), 215(100), 141(17)
6-deoxo-28-nor-3-DHTc	6-deoxo-28-norTEc	0.605	516(M+, 73), 501(65), 459(25), 426(23), 411(36), 305(38), 230(26), 215(100), 141(24)
	6-deoxo-28-norTYc	0.523	516(M+, 21), 501(5), 459(4), 426(60), 411(59), 305(10), 230(32), 215(100), 141(16)
6-deoxo-28-norTYc	6-deoxo-28-nor-3-DHTb	0.615	442(M+, 74), 427(10), 246(12), 231(100), 217(22), 163(20), 141(14)
	6-deoxo-28-norTEc	0.605	516(M+, 71), 501(62), 459(25), 426(23), 411(35), 305(36), 230(26), 215(100), 141(23)
	6-deoxo-28-norCSb	0.619	484(M+, 51), 469(16), 288(15), 273(100), 205(24), 141(21)
6-deoxo-28-norCSb	28-norCSb	0.866	498(M+, 100), 483(8), 399(3), 358(11), 328(8), 287(35), 141(54)
28-norCSb	CSb	1.000	512(M+, 87), 358(34), 327(11), 287(30), 155(100)
CSb	26-norCSb	0.900	498(M+, 100), 483(8), 399(13), 358(28), 328(10), 287(42), 141(94)
[26,28-2H6]CSb	[26-2H3]28-norCSb	0.863	501(M+, 100), 486(8), 399(4), 358(16), 328(11), 287(42), 144(52)

^aAnalyzed by its trimethylsilyl ether.

^bAnalyzed by its bismethaneboronate.

^cAnalyzed by its methaneboronate-trimethylsilyl ether.

^dRelative retention time (RR_t) with respect to castasterone (26.80 min).