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. Author manuscript; available in PMC: 2017 Nov 2.
Published in final edited form as: Angew Chem Int Ed Engl. 2016 Oct 10;55(45):14077–14080. doi: 10.1002/anie.201608446

Table 2.

Scope of Branched-Selective Allylation Reaction.[a,b,c]

graphic file with name nihms835900t2.jpg
[a]

Conditions: 1.0 or 0.5 mmol imine (1.0 equiv), allene (1.2 equiv), copper(II) acetate (0.05 equiv), DCyPE (0.06 equiv), DMMS (5.0 equiv), tert-butanol (2.0 equiv) in MTBE (1.0 or 2.0 mL), see Supporting Information for further details.

[b]

Average isolated yield from two experiments.

[c]

Diastereomer ratio measured by 1H NMR of the crude reaction mixture.