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. 2016 Dec 16;2(12):954–966. doi: 10.1021/acscentsci.6b00291

Table 3. Dynamic Hyperpolarizabilities [βHRS, (× 10–30 esu)]a and Depolarization Ratios (ρ) Determined from Hyper-Rayleigh Experiments.

  800 nm 840 nm 1064 nm 1300 nm 1320 nm 1340 nm 1500 nm ρb
RuPZnc 200 ± 30 700 ± 100   1300 ± 100 1320 ± 70 90 ± 40 110 ± 4 3.8
RuPZnRu (1) 190 ± 30 450 ± 70 1000 ± 100 260 ± 80 660 ± 40 710 ± 40 4600 ± 1200 1.7
P1RuPZnP1Ru (2) 220 ± 10 510 ± 80 300 ± 40   180 ± 70   600 ± 100 1.9
P1RuRfPZnP1Ru (3) 180 ± 10 390 ± 60         30 ± 4 1.8
a

Total HRS intensity as noted in the text at the indicated wavelength.

b

Measured at λinc = 800 nm.

c

Hyperpolarizability values for RuPZn have been reported previously.16,22 A blank entry indicates a βHRS value <30 × 10–30 esu.